We present high-resolution X-ray spectroscopy of the merging galaxy cluster A3667 with XRISM/Resolve. Two observations, targeting the cluster X-ray core and the prototypical cold front, were performed with exposures of 105 and 276 ks, respectively. We find that the gas in the core is blueshifted by vz ∼ −200 km s−1 relative to the brightest cluster galaxy, while the low-entropy gas inside the cold front is redshifted by vz ∼ 200 km s−1. As one moves further off-center across the front, the line-of-sight (LoS) velocity changes significantly, by ∆vz=535−154+167 km s−1, back to the value similar to that in the core. There are no significant LoS velocity gradients perpendicular to the cluster symmetry axis. These features suggest that the gas forming the cold front is flowing in the plane oriented along the LoS, supporting an offset merger scenario in which the main cluster has passed in front of the subcluster and induced rotation of the core gas in the plane perpendicular to the sky. The region just inside the front exhibits the largest LoS velocity dispersion seen across two pointings, σz ∼ 420 km s−1, which can be interpreted as a developing turbulence or a projection of the LoS velocity shear within the front. The large LoS velocity jump across the cold front, combined with the lack of Kelvin─Helmholtz instability on the surface of the front, suggests some mechanism to suppress it. For example, a magnetic field with B > 5 μG is required if the cold front is stabilized by magnetic draping.
