Context. The H3O+ molecule probes the chemistry and the ionization rate of dense circumnuclear gas in galaxies.
Aims: We use the H3O+ molecule to investigate the impact of starburst and AGN activity on the chemistry of the molecular interstellar medium.
Methods: Using the JCMT, we have observed the 32+ – 22+ 364 GHz line of p-H3O+ towards the centres of seven active galaxies.
Results: We have detected p-H3O+ towards IC 342, NGC 253, NGC 1068, NGC 4418, and NGC 6240. Upper limits were obtained for IRAS 15250 and Arp 299. We find large H3O+ abundances (N(H3O+)/N(H2) ≳ 10-8) in all detected galaxies apart from in IC 342 where it is about one order of magnitude lower. We note, however, that uncertainties in N(H3O+) may be significant due to lack of definite information on source size and excitation. We furthermore compare the derived N(H3O+) with N(HCO+) and find that the H3O+ to HCO+ column density ratio is large in NGC 1068 (24), moderate in NGC 4418 and NGC 253 (4-5), slightly less than unity in NGC 6240 (0.7) and lowest in IC 342 (0.2-0.6). We compare our results with models of X-ray and photon dominated regions (XDRs and PDRs).
Conclusions: For IC 342 we find that a starburst PDR chemistry can explain the observed H3O+ abundance. For the other galaxies, the large H3O+ columns are generally consistent with XDR models. In particular for NGC 1068 the elevated N(H3O+)/N(HCO+) ratio suggests a low column density XDR. For NGC 4418 however, large HC3N abundances are inconsistent with the XDR interpretation. An alternative possibility is that H3O+ forms through H2O evaporating off dust grains and reacting with HCO+ in warm, dense gas. This scenario could also potentially fit the results for NGC 253. Further studies of the excitation and distribution of H3O+ – as well as Herschel observations of water abundances – will help to further constrain the models.

